• simplest addition polymer
  • commonly known as polyethylene(PE)
  • produced by addition polymerisation of ethene monomers.
  1. at high temperature and pressure, and in presence of catalyst → carbon-carbon double bonds of ethene molecules (monomers) break
  2. each monomer forms single bonds with 2 other monomers. eventually → polymer poly(ethene) is formed

polymer is usually made of similar units joined together. these units are known as repeat units

Definition

Repeating unit of a polymer is the simplest formula that contains the smallest part of a polymer molecule #ChemistryDefinitions

  • repeat unit of polyethene is:

Full Process

StepElaborateimage
1Write out formula of several monomer molecules (ethene)
2During addition polymerisation → one of the covalent bonds in the carbon carbon double bond in each monomer molecules breaks → converting monomer molecules to repeat units.
3Repeat units joined together by forming carbon carbon single bonds to form a molecule of addition polymer (macromolecule)

Formula of polymer can be written using its repeating unit. formula of polyethene can simply be written as: letter n represents a large number. may ethene molecules are required to form each poly(ethene) molecule


Balanced Chemical Equation for Addition Polymerisation of Ethene using Displayed Formula


Physical Properties of Polyethene: flexible but difficult to break as it is a strong material Uses of Polyethene: making plastic bottles, plastic bags, pails, toys, cling films.