• simplest addition polymer
  • commonly known as polyethylene(PE)
  • produced by addition polymerisation of ethene monomers.
  1. at high temperature and pressure, and in presence of catalyst carbon-carbon double bonds of ethene molecules (monomers) break
  2. each monomer forms single bonds with 2 other monomers. eventually polymer poly(ethene) is formed

polymer is usually made of similar units joined together. these units are known as repeat units

Definition

Repeating unit of a polymer is the simplest formula that contains the smallest part of a polymer molecule #ChemistryDefinitions

  • repeat unit of polyethene is:

Full Process

StepElaborateimage
1Write out formula of several monomer molecules (ethene)
2During addition polymerisation one of the covalent bonds in the carbon carbon double bond in each monomer molecules breaks converting monomer molecules to repeat units.
3Repeat units joined together by forming carbon carbon single bonds to form a molecule of addition polymer (macromolecule)

Formula of polymer can be written using its repeating unit. formula of polyethene can simply be written as: letter n represents a large number. may ethene molecules are required to form each poly(ethene) molecule


Balanced Chemical Equation for Addition Polymerisation of Ethene using Displayed Formula


Physical Properties of Polyethene: flexible but difficult to break as it is a strong material Uses of Polyethene: making plastic bottles, plastic bags, pails, toys, cling films.