• Compounds which are good conductors of electricity when molten / aqueous solution
  • Electrolytes are electrolytic conductors which decompose to form new substances when they conduct electricity
  • Electricity can be conducted due to presence of positive and negative ions (or cations and anions) which can move freely across molten / aqueous electrolyte and act as charge carriers
  • Electrolytes usually made of:
Classification of electrolytes:
Strong Electrolytes:
  • Compounds that ionise completely / almost completely to form high concentration of mobile ions in aqueous solution or molten form
  • Greater the concentration of mobile ions in electrolyte the greater is its capacity to carry charges / conduct electricity the stronger the electrolyte
    • E.g. - sodium chloride ionic compound with giant ionic lattice structure melted or dissolved in water dissociated completely to form freely moving sodium and chloride ions.
    • Same with pure sulfuric acid
    • Other examples of strong electrolytes include strong acids Strong Acids, strong alkalis Strong and Weak Alkalis
Weak Electrolytes
  • Compounds that ionise partially form mobile ions in the aqueous solution / molten form
  • When concentration of mobile ions lower in electrolyte lesser is its capacity carry charges / conduct electricity the weaker the electrolyte
    • E.g. - pure ethanoic acid
      • Covalent compound with the simple molecular structure when mixed with water ethanoic acid, being weak acid ionises partially to form low concentration of hydrogen and ethanoate ions.
      • Only some of the ethanoic acid molecules ionised thus concentration of ions (ethanoate and hydrogen) is less compared to concentration of ethanoic acid molecules present
    • Same for Ammonia.
    • Other examples of weak electrolytes Weak Acids, Strong and Weak Alkalis

Non electrolytes
  • Compounds that do not ionise to form ions in aqueous solution or molten form.
  • Example: organic liquids like benzene, tetrachloromethane, ethanol which are covalent compounds which may or may not dissolve in water.
  • If it does not dissolve it will not form aqueous solution
  • If it dissolves in water but does not ionise (e.g. sugar) it will also not be an electrolyte

Examples of Electrolyte